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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Spectator ligand ： ウィキペディア英語版 Spectator ligand In coordination chemistry, a spectator ligand is a ligand that does not participate in chemical reactions of the complex. Instead, spectator ligands (vs "actor ligands") occupy coordination sites.〔}〕 Spectator ligands tend to be of polydentate, such that the M-spectator ensemble is inert kinetically. Although they do not participate in reactions of the metal, spectator ligands influence the reactivity of the metal center to which they are bound. There are several different classes of ligand that can be considered spectator ligands. A few examples of common spectator ligands include trispyrazolylborates (Tp), cyclopentadienyl ligands (Cp), and many chelating diphosphines such as 1,2-bis(diphenylphosphino)ethane ligands (dppe). Varying the substituents on the spectator ligands greatly influences the solubility, stability, electronic and steric properties of the metal complex. ==References== 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Spectator ligand」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.